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Rusting of Iron

Exam code: 5070
Written by: Ashika|Reviewed by: Caroline Carroll|Updated 2 July 2026

Rusting of Ironvideo

Rusting of Iron

Rusting of Iron

  • Rust is a chemical reaction between iron, water and oxygen to form the compound hydrated iron(III) oxide (rust)

  • Oxygen and water must be present for rust to occur

  • During rusting, iron is oxidised 

iron +  water + oxygen  →  hydrated iron(III) oxide 

 Investigating rusting

  • To investigate the conditions required for rusting, prepare three test tubes as shown in the diagram

  • The oil in the 2nd tube keeps out air and the water has been boiled so that no air is left in it

  • The calcium chloride in the 3rd tube is used to remove any moisture in the air

  • After a few days, the iron nail in the 1st tube will be the only nail to show signs of rust

Conditions for rusting, IGCSE & GCSE Chemistry revision notes

Diagram showing the requirements of oxygen and water for rust to occur: only the nail on the left rusts

Rust prevention methods

Barrier methods

  • Rust can be prevented by coating iron with barriers that prevent the iron from coming into contact with water and oxygen

  • However, if the coatings are washed away or scratched, the iron is once again exposed to water and oxygen and will rust

Barrier Methods of Rust Prevention table, IGCSE & GCSE Chemistry revision notes